JEE Main 2022 (25 Jun, Shift 2) Chemistry Q77: Which of…

Question

Which of the following conditions or reaction sequence will NOT give acetophenone as the major product ?

Accepted Answer

Option 3: [drawn: carbonyl C (C=O) with $\mathrm{C_6H_5}$ at lower left and $\mathrm{OC_2H_5}$ at lower right] + 2 $\mathrm{CH_3MgBr}$

Answer

(a) [drawn: carbonyl C (C=O) with $\mathrm{C_6H_5}$ at lower left and H at lower right] + $\mathrm{CH_3MgBr}$  (b) $\mathrm{Na_2Cr_2O_7}$, $\mathrm{H^+}$

Answer

(a) [drawn: carbonyl C (C=O) with $\mathrm{H_3C}$ at lower left and H at lower right] + $\mathrm{C_6H_5MgBr}$  (b) PCC, DCM

Answer

[drawn: carbonyl C (C=O) with $\mathrm{C_6H_5}$ at lower left and $\mathrm{OC_2H_5}$ at lower right] + 2 $\mathrm{CH_3MgBr}$

Answer

[drawn: carbonyl C (C=O) with $\mathrm{C_6H_5}$ at lower left and Cl at lower right] + $\mathrm{CH_3MgBr}$ + $\mathrm{CdCl_2}$

JEE Main 25 June 2022, Shift 2, Chemistry Q77

Same idea in other shifts