JEE Main 2025 (8 Apr, Shift 2) Chemistry Q69: Amines

Question

$A \xrightarrow[	ext{(ii) H}_3	ext{O}^+]{	ext{(i) NaOH}} B \xrightarrow[	ext{(ii) H}_2	ext{SO}_4, \Delta]{	ext{(i) EtOH}} C$
'A' shows positive Lassaign's test for N and its molar mass is 121.
'B' gives effervescence with aq $\mathrm{NaHCO_3}$.
'C' gives fruity smell.
Identify A, B and C from the following.

Accepted Answer

Option 1: A = [benzene ring with $\mathrm{CONH_2}$], B = [benzene ring with $\mathrm{CO_2H}$], C = [benzene ring with $\mathrm{CO_2Et}$]

Answer

A = [benzene ring with $\mathrm{CONH_2}$], B = [benzene ring with $\mathrm{CO_2H}$], C = [benzene ring with $\mathrm{CO_2Et}$]

Answer

A = [benzene ring with $\mathrm{CH_2NHNH_2}$], B = [benzene ring with $\mathrm{CO_2H}$], C = [benzene ring with $\mathrm{CO_2Et}$]

Answer

A = [4-aminobenzaldehyde: benzene ring with CHO and para $\mathrm{NH_2}$], B = [4-aminobenzoin: $\mathrm{4	ext{-}H_2N	ext{-}C_6H_4	ext{-}CH(OH)	ext{-}C(=O)	ext{-}C_6H_4	ext{-}4	ext{-}NH_2}$], C = [$\mathrm{4	ext{-}H_2N	ext{-}C_6H_4	ext{-}CH(OH)	ext{-}C(OH)(OEt)	ext{-}C_6H_4	ext{-}4	ext{-}NH_2}$]

Answer

A = [2-aminobenzaldehyde: benzene ring with ortho CHO and $\mathrm{NH_2}$], B = [benzene ring with ortho $\mathrm{NH_2}$ and $\mathrm{CO_2H}$], C = [benzene ring with ortho NHEt and $\mathrm{CO_2Et}$]

JEE Main 8 April 2025, Shift 2, Chemistry Q69

Same idea in other shifts