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Saturday, 31 October

JEE Main 2024 · ChemistryMultiple choiceMatch the listMediumRecall

JEE Main 8 April 2024, Shift 2, Chemistry Q77

Question 77 of 90 in this shift, Chemistry question 17 of 30, Section A.

Match List - I with List - II. List - I (Reactions) | List - II (Products) (A) aniline (C6H5NH2\mathrm{C_6H_5NH_2}) with (i) NaNO2+HCl\mathrm{NaNO_2 + HCl} (ii) H2O\mathrm{H_2O}, warm | (I) salicylaldehyde (benzene ring with OH and ortho CHO) (B) phenol with Na2Cr2O7\mathrm{Na_2Cr_2O_7}, H2SO4\mathrm{H_2SO_4} | (II) phenol (benzene ring with OH) (C) phenol with (i) CHCl3\mathrm{CHCl_3} + aq NaOH (ii) H+\mathrm{H^+} | (III) salicylic acid (benzene ring with OH and ortho COOH) (D) phenol with (i) NaOH (ii) CO2\mathrm{CO_2} (iii) H+\mathrm{H^+} | (IV) p-benzoquinone (cyclohexadienedione ring with two C=O para) Choose the correct answer from the options given below :

The figure, in words

List-I shows reactant structures with reagents over arrows: (A) aniline, (i) NaNO2+HCl (ii) H2O, warm; (B) phenol, Na2Cr2O7/H2SO4; (C) phenol, (i) CHCl3+aq NaOH (ii) H+; (D) phenol, (i) NaOH (ii) CO2 (iii) H+. List-II shows products: (I) 2-hydroxybenzaldehyde, (II) phenol, (III) 2-hydroxybenzoic acid, (IV) p-benzoquinone.
  1. (1)(A)-(I), (B)-(IV), (C)-(II), (D)-(III)
  2. (2)(A)-(III), (B)-(II), (C)-(I), (D)-(IV)
  3. (3)(A)-(II), (B)-(IV), (C)-(I), (D)-(III)Official answer
  4. (4)(A)-(IV), (B)-(II), (C)-(III), (D)-(I)

Official answer

Option 3

NTA final key.

Chapter
Alcohols, Phenols and Ethers
Topic
Alcohols and Phenols
Idea tested
Reimer-Tiemann Reaction

Same idea in other shifts

Asked 9× in all
  1. 6 Apr 2024, Shift 1 · Q78In Reimer - Tiemann reaction, phenol is converted into salicylaldehyde through an intermediate. The structure of intermediate is __________.EasyDiagram basedHas a figure
  2. 30 Jan 2024, Shift 2 · Q76Salicylaldehyde is synthesized from phenol, when reacted withEasySingle correct
  3. 25 Jun 2022, Shift 1 · Q76The intermediate X, in the reaction : [figure: CHCl3\mathrm{CHCl_3} + Aq. NaOH + benzene ring with OH substituent, arrow to [X]; below [X] an…EasyDiagram basedHas a figure
  4. 27 Jun 2022, Shift 2 · Q75Match List I with List II. List I | List II A. [drawn: benzene ring bearing OH →\rightarrow benzene ring bearing OH and, on a…MediumMatch the listHas a figure
  5. 4 Aug 2021, Shift 1 · Q46Match List I with List II List I List II A. Kolbe's Reaction I. [structure: benzene ring with a CHO substituent] B. Gatterman-Koch…MediumMatch the listHas a figure
  6. 26 Feb 2021, Shift 1 · Q45Identify the major products A and B respectively in the following reactions of phenol : [reaction scheme, see figure_note]MediumDiagram basedHas a figure
  7. 22 Jul 2021, Shift 2 · Q45An organic compound A (C6H6O\mathrm{C_6H_6O}) gives dark green colouration with ferric chloride. On treatment with CHCl3\mathrm{CHCl_3} and KOH,…MediumDiagram basedHas a figure
  8. 6 Sep 2020, Shift 2 · Q50A solution of phenol in chloroform when treated with aqueous NaOH gives compound P as a major product. The mass percentage of carbon in P…EasyNumerical value

Question text from the official JEE Main paper published by NTA; answer from the final answer key. Chapter, topic and idea tags, difficulty and skill are Lumi’s. This question needs a figure we do not reproduce; it is described in words above. Lumi analyses 108 of the 174 JEE Main shifts held from 2017 to 2026.