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Saturday, 31 October

JEE Main 2023 · ChemistryMultiple choiceDiagram basedMediumApplication

JEE Main 13 April 2023, Shift 1, Chemistry Q74

Question 74 of 90 in this shift, Chemistry question 14 of 30, Section A.

In the following reaction 'X' is CH3(CH2)4CH3→ΔAnhy.AlCl3/HCl\mathrm{CH_3(CH_2)_4CH_3}\xrightarrow[\Delta]{\text{Anhy.AlCl}_3/\text{HCl}} 'X' (major product)

The figure, in words

Reaction scheme of n-hexane with anhydrous AlCl3/HCl, heat; option 3 is a cyclohexane ring structure.
  1. (1)CH3(CH2)4CH2Cl\mathrm{CH_3(CH_2)_4CH_2Cl}
  2. (2)Cl-CH2-(CH2)4-CH2-Cl\mathrm{Cl\text{-}CH_2\text{-}(CH_2)_4\text{-}CH_2\text{-}Cl}
  3. (3)[figure: cyclohexane ring drawn with H2C and CH2 groups]
  4. (4)CH3CH−(CH2)2CH3\mathrm{CH_3CH-(CH_2)_2CH_3} with a CH3\mathrm{CH_3} substituent on the first CHOfficial answer

Official answer

Option 4

NTA final key.

Same idea in other shifts

Asked 2× in all
  1. 2 Apr 2026, Shift 2 · Q64The compound (X) on heating in the presence of anhydrous AlCl3_3 and HCl gas gives 2,4-dimethyl pentane (ii) aromatization gives toluene…EasySingle correct

Question text from the official JEE Main paper published by NTA; answer from the final answer key. Chapter, topic and idea tags, difficulty and skill are Lumi’s. This question needs a figure we do not reproduce; it is described in words above. Lumi analyses 108 of the 174 JEE Main shifts held from 2017 to 2026.