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Saturday, 31 October

JEE Main 2020 · ChemistryMultiple choiceDiagram basedHardConceptual

JEE Main 3 September 2020, Shift 2, Chemistry Q42

Question 42 of 75 in this shift, Chemistry question 17 of 25.

The decreasing order of reactivity of the following compounds towards nucleophilic substitution (SN2\mathrm{S_N2}) is : (I) [figure] (II) [figure] (III) [figure] (IV) [figure]

The figure, in words

Four benzene-type rings (hexagon with circle), drawn with commas between and labelled (I) to (IV). (I): ring with CH2Cl on a vertical line above it, no other substituent. (II): ring with CH2Cl above; one NO2 attached at the upper right of the ring next to the CH2Cl carbon and a second NO2 at the lower right. (III): ring with CH2Cl on a vertical line above; one NO2 at the lower right of the ring and a second NO2 on a vertical line below the ring at lower left. (IV): ring with CH2Cl on a vertical line above; O2N at the lower left and NO2 at the lower right.
  1. (1)(III) > (II) > (IV) > (I)
  2. (2)(IV) > (II) > (III) > (I)
  3. (3)(II) > (III) > (I) > (IV)
  4. (4)(II) > (III) > (IV) > (I)Official answer

Official answer

Option 4

NTA final key (Sep 2020).

Same idea in other shifts

Asked 3× in all
  1. 4 Apr 2024, Shift 2 · Q76Find out the major product formed from the following reaction. [Me : −CH3-\mathrm{CH_3}] →Me2NH (2 equiv)\xrightarrow{\mathrm{Me_2NH\ (2\ equiv)}}HardDiagram basedHas a figure
  2. 9 Apr 2024, Shift 1 · Q73Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : SN2\mathrm{S_N2}…EasyAssertion–reason

Question text from the official JEE Main paper published by NTA; answer from the final answer key. Chapter, topic and idea tags, difficulty and skill are Lumi’s. This question needs a figure we do not reproduce; it is described in words above. Lumi analyses 108 of the 174 JEE Main shifts held from 2017 to 2026.