Thermodynamics

Physics · Class 11

Simulation · Physics · Class 11

A cycle on the P–V diagram

From the lesson Isochoric, isobaric and cyclic processes in Thermodynamics. Change the values and watch what happens.

A cycle on the P–V diagramPhysics · Class 11

The idea behind it

NCERT §11.8.4, §11.8.5, §11.8.6

  • Isochoric (V constant): the gas neither does work nor has work done on it. All the heat absorbed goes into internal energy and raises the temperature; the rise for a given heat is set by the specific heat at constant volume.
  • Isobaric (P constant): the gas does work W = P(V₂ − V₁) = μR(T₂ − T₁).
  • In an isobaric process the temperature changes, so U changes too. The heat absorbed goes partly into internal energy and partly into work; the temperature rise for a given heat is set by the specific heat at constant pressure.
  • That is why C_p > C_v: at constant pressure part of the heat leaves as work, so more heat is needed for the same temperature rise.
  • Cyclic process: the system returns to its initial state. U is a state variable, so ΔU = 0 over a cycle, and the net heat absorbed equals the net work done by the system.
  • On a P–V diagram the work in a process is the area under its curve; for a cycle, the net work is the area enclosed by the loop.
  • Summary of the first law in the four special processes: isothermal ΔU = 0, Q = W; adiabatic Q = 0, W = −ΔU; isochoric W = 0, Q = ΔU; isobaric Q = ΔU + PΔV.