Chemistry

Class 12

Chemistry · Class 12 · Chapter 7

Alcohols, Phenols and Ethers

13 lessons 97 min 2 simulations

Alcohols, phenols and ethers are the organic compounds built around a C–O single bond: –OH on an aliphatic carbon, –OH on an aromatic ring, or oxygen bridging two carbon groups. The chapter classifies and names them, relates their structure to boiling point, solubility and acidity, and works through their preparation, the reactions that break O–H or C–O bonds, oxidation, ring substitution in phenols and anisole, and the two alcohols made on an industrial scale.

What the exam asks

NEET tests the acidity order of substituted phenols against pKa, reagents for each preparation (hydroboration, Grignard, cumene, Williamson), the Lucas test, products of controlled oxidation (PCC, CrO₃, KMnO₄, Cu at 573 K), the named phenol reactions (Kolbe, Reimer–Tiemann), and the cleavage of ethers by HI. Marks are lost by reading a larger pKa as a stronger acid, pairing a tertiary halide with an alkoxide in Williamson synthesis, and breaking the wrong C–O bond in anisole.

Lessons

13 lessons · 97 min